Live data from Hacker News

Why is everyone trying to build a solid-state battery?

construction-physics.com

81–90 of 331 posts

Re: Why is everyone trying to build a solid-state battery?

#81
> because the liquid electrolyte currently used in batteries is flammable, replacing it with a solid could make batteries safer and less susceptible to fire.

The problem is primarily that batteries are storing a lot of energy, which can be released when things go wrong. The electrolytes (technically, the solvents) typically don't ignite under 750°F or so, which makes them less flammable than a lot of other common materials, and far less of a concern than, say, the lithium metal.

Re: Why is everyone trying to build a solid-state battery?

#82
post #58

Earlier quoted context omitted.

The next revolution will be small scale generation. Fuel cells, extremely efficient cheap solar, even smaller modular reactors, etc. I live in western Pennsylvania and have both natural gas and electric service, a roof and 1/3 acre of land to utilize. I would love to get rid of at least one of my utility bills and I’m becoming more interested in decoupling from the electric grid than natural gas service. I dream of a…

With modern heat pumps and induction stoves getting off of natural gas is fairly easy for most people and saves money in the long run. Meanwhile the grid is switching to renewables so getting off gas is your best investment. You can get of electric too, but on your 1/3rd acre that probably means significant lifestyle compromises - I will be impressed if you are willing to live with them.

Batteries are cheap enough to build (using a commercial installer completely kills the economics, because you're paying five to ten times the actual cost in the US) a reasonable size personal battery bank (~100+ kwh), paired with some overkill solar, to totally replace the grid in a lot of cases. GP isn't limited to rooftop solar with 1/3rd an acre, so they can do it quite cheap if they want.

Re: Why is everyone trying to build a solid-state battery?

#83
If you know a bit about electronics, you might be a bit surprised by the term 'solid-state battery'. It's a poor analogue to the more common usage of solid-state with semiconductors, integrated circuits, etc. -- a "solid-state" cell is still a chemical cell. It's not a paradigm shift on the level of, say, replacing a relay with a MOSFET.

Re: Why is everyone trying to build a solid-state battery?

#84
post #54

Earlier quoted context omitted.

It should be relatively straightforward to imagine — we already have that in gasoline-powered internal combustion engines. The Watt-hours per kilogram of good Lithium Ion batteries is around 250-280 Wh/Kg; for Lithium Iron Phosphate it's about 180 Wh/kg, and for Sodium-Ion about 170 Wh/Kg. The raw energy in gasoline is about 12,300 Wh/Kg but automobile internal combustion engines get only about 20-30% efficiency yiel…

> With a 130Lb/60kg battery instead, and saving the weight of the ICE engine and fuel system, the overall car design could go much more lightweight, regaining a lot of performance and range, all while gaining the huge torque of electric motors. I think you're underselling it, even. A typical like-for-like modern EV is only marginally heavier than the ICE equivalent. If we were able to drop the weight of the battery b…

Yes, underselling a bit for sure! I didn't even want to get into the optimizations available if cars were really designed for lightweight when the entire motors+battery is only 100-150kg, and the battery can be low and centered.

We could go for performance, trading off some battery for four inboard motors (fully sprung weight) with half-shafts and CV joints, steel space-frame chassis and carbon fiber body — it could put many supercars to shame.

Going for range, same light-weighting, but less powerful motors and adding more battery, the range could get silly long at something like 1000 miles for 100kg of battery.

For the kind of long range options another poster mentioned, with 100 kg for 1000 miles, a few 10-kilo swappable battery packs could make it easy to trade luggage space for range, or bring them to a charge station only occasionally, but not lug them around for most in-town trips.

No question, we could go wild!

Re: Why is everyone trying to build a solid-state battery?

#85
post #81

> because the liquid electrolyte currently used in batteries is flammable, replacing it with a solid could make batteries safer and less susceptible to fire. The problem is primarily that batteries are storing a lot of energy, which can be released when things go wrong. The electrolytes (technically, the solvents) typically don't ignite under 750°F or so, which makes them less flammable than a lot of other common mat…

I wonder about the youtube videos of someone driving a screwdriver through a battery pack.

Is that the electrical discharge, then the lithium going off, then the electrolytes?

Re: Why is everyone trying to build a solid-state battery?

#86
post #81

> because the liquid electrolyte currently used in batteries is flammable, replacing it with a solid could make batteries safer and less susceptible to fire. The problem is primarily that batteries are storing a lot of energy, which can be released when things go wrong. The electrolytes (technically, the solvents) typically don't ignite under 750°F or so, which makes them less flammable than a lot of other common mat…

Isn't the key difference that flammable solids have a limited reaction surface when they burn, whereas flammable liquids can be wildly unpredictable?

Re: Why is everyone trying to build a solid-state battery?

#87
post #81

> because the liquid electrolyte currently used in batteries is flammable, replacing it with a solid could make batteries safer and less susceptible to fire. The problem is primarily that batteries are storing a lot of energy, which can be released when things go wrong. The electrolytes (technically, the solvents) typically don't ignite under 750°F or so, which makes them less flammable than a lot of other common mat…

This isn't true for most lithium ion chemistries.

The liquid electrolyte is the thing that releases most energy when the battery burns, more than the anode and cathode. Some also have a very low self ignition temperature.

Re: Why is everyone trying to build a solid-state battery?

#88
post #23

Earlier quoted context omitted.

Gasoline has 10x the energy (MJ/Kg) than TNT, but it's not a "bomb". Being a "bomb" is about energy release rate . A battery is still controlled by its chemistry.

Liquid gasoline does not have anywhere near the energy of TNT, or even a battery for that matter. It contains basically zero releasable energy. It needs oxygen or another oxidizer to react with to actually release any energy. TNT and batteries' energy density calculations include the oxidizer and the oxidizer is in close proximity to the fuel (molecularly so in the case of TNT). If you 10x the "energy content" of gas…

[deleted]

Re: Why is everyone trying to build a solid-state battery?

#89
post #47

Earlier quoted context omitted.

Not all batteries need to be mobile. A 1 GWh grid scale battery takes up about 4 hectares at the moment. The UKs total energy use is about 2,000GWh a day. It would need to use 240,000 hectares to store all energy requirements (eletric, transport, heating etc) for a whole month. Even in extreme cold conditions it would last a couple of weeks. That would be about 1% of land use.

Storing a month of energy use doesn't make any sense when it comes to renewable grids. Since you don't have to mine/extract and transport an inventory, far far less storage is required.

Doesn't that depend on the sources of energy though? Pretty much constant short and mid term supply like geothermal, hydro, tides, etc vs unpredictable or variable in the short term like wind and solar.

As a society relying on solar, I'd want to have more of a buffer than one that relies on hydro.

Re: Why is everyone trying to build a solid-state battery?

#90
post #81

> because the liquid electrolyte currently used in batteries is flammable, replacing it with a solid could make batteries safer and less susceptible to fire. The problem is primarily that batteries are storing a lot of energy, which can be released when things go wrong. The electrolytes (technically, the solvents) typically don't ignite under 750°F or so, which makes them less flammable than a lot of other common mat…

IIUC, the main problem with the current Li batteries is that the two plates can over time grow material that will 1) degrade performance; and 2) make it more likely to short circuit and catch fire. Similarly with electric car batteries after accidents where the battery is damaged, short circuits, and then catches fire.

So the main risk here would be the likelyhood of short circuiting under different failure scenarios.

Post reply on HN