Earlier quoted context omitted.
You just answered your own question. Developing nations aren't at 100% renewable because they already have a large amount of installed non-renewables.
Err...no. Developing countries tend to not have a large amount of anything. Definitionally they're poor and under-resourced. If their economies are growing, the grids are constantly playing catch-up with demand. Otherwise they're in a state of managed decline, or are an actual dumpster fire. Whatever the case may be, the one thing they don't have is reliable base generation capability. A safety net for when renewable…
Developing -> Developed in my original comment.