Earlier quoted context omitted.
This paper "weakly solves" Othello. That means that we know for the initial board state both 1) the final win/lose/draw outcome (it's a draw), and 2) the sequence of moves that should be taken by perfect players to get there (Figure 1, right). In particular, the paper does not "strongly solve" Othello. If you have an arbitrary board state, 1) and 2) are are not necessarily known for it. That means it's still possible…
>That means it's still possible to win a game by intentionally deviating from the perfect sequence Someone with perfect strategy would have an answer for any deviation. Playing imperfectly would likely get you into a losing position. There is no way to go from a game being drawn if played perfectly to being winning if the then loser were to be using perfect strategy.
This does have to be mutual though, if only one side plays imperfectly, then the other can always force at least a draw.
So if you know the other side is incapable of playing perfectly, it could be rational to deviate.