Earlier quoted context omitted.
Depends which keyboard I use, but sometimes, same here. My main work PC has a 1991 Model M on it. Best PC keyboard ever made, and I have about 5 of them, carefully kept since people were throwing them away in the 1990s. I remap Caps Lock to Super, and I'm good to go. I really don't need media-control keys or anything, or a right Super key. I am trialling an early model of Das Keyboard on my Mac. The volume-control di…
On windows ctrl+esc is the same as the super key.
I mean, yes, Ctrl+Esc opens the Start menu, which the Windows key also opens.
But the Windows key -- before MS renamed it, the Super key -- is a single modifier key in its own right.
Win+R = Run
Win+D = hide all windows and show Desktop
Win+E = open Explorer
Win+SysRq = open System Properties.
There are dozens of them; these are just a few of the ones I personally use.
Other OSes and desktops use it for other things. In GNOME it opens the Overview. In Unity it opens the search function, and Super+A opens the app search function, and Super+S opens the virtual-desktop switcher, etc.
It has lots and lots of uses, and opening the Start menu is just one. Ctrl+Esc doesn't do any of these other functions, and it cannot do them because it's not a modifier key so you can't use it plus another key at the same time.
People often say that they can't use an old, pre-Win95 keyboard because they need the Windows key. What I am pointing out is that it's easy to work around that, by sacrificing another key that's not very useful: Caps Lock.
This also sits in the same location as Ctrl on the old Sun keyboards, which is a convenient position for a modifier key -- it's easy to press CapsLock with your little finger while using the rest of the hand to press the other key of the combination.