Earlier quoted context omitted.
LHR is capacity constrained right now so they don't have slots to add more flights. Hopefully the runway expansion will be finished by the time Boom airliners are actually in service.
American would swap this in for a plane which is using an existing takeoff/landing slot. Heathrow is also passenger-capacity-constrained right now, but that's more to do with understaffing.
Have to be charging a great deal to the small number of passengers for it to be worth swapping in to a fully loaded 777 spot