The main counterargument I see to this happening goes like: any world leader calling for nuclear armageddon will not be obeyed/will be assassinated because they cannot convince the entire chain of command to commit suicide. This seems flaky to me. One other thought I had is that perhaps that we are not capable of nuclear armageddon, because this has not been tested end-to-end, although ICBMs and nukes have been tested quite extensively.
What does HN think? Could it happen? And why do we assume that the tech is sufficiently advanced to e.g. take out every major city at the push of a button?