Earlier quoted context omitted.
Unless you can fuse it into helium.
If you have the tech to fuse hydrogen the amount of fuel you would need for a nearly unlimited amount of energy is tiny, you would save very little by harvesting it off a comet/asteroid.
This is of course well beyond our current capabilities, but it's not something that's impossible to consider in the medium-distant future. Plus, even if you expend a colossal amount of energy accelerating you're still talking about thousands of years for the journey where you'll need to keep those reactors running for the entire trip (there is no useful solar collection in deep space) having a literal mountain of fuel to start with is important.