Earlier quoted context omitted.
https://en.wikipedia.org/wiki/Polymer_fume_fever https://en.wikipedia.org/wiki/Polytetrafluoroethylene#Safety
Those articles describe PTFE as "stable and non-toxic at lower temperatures", starting to degrade into concerning and toxic byproducts at 500F/260C. As a rule, I try not to let my rain jacket reach 260C, but your local weather may differ?
People who own birds are suggested to not use PTFE coated pans. Birds are much more sensitive to the offgased chemicals and there are numerous instances of people accidentally killing pet birds from these fumes, so it definitely happens.