This sounds like it could be rather dangerous, no? Connecting up a bunch of old lithium cells of unknown origin and using them hard. I'd also worry about an insurance claim being denied if it burned my house down. However, I very much approve of the DIY ingenuity and repurposing of old stuff.
Kind of dangerous seems like quite the understatement, considering the nature of lithium batteries! It'd be fun to play with something like this for the learning, but I wouldn't actually run one unless it was in its own shed, many dozens of yards from the nearest anything else. Lithium fires are no joke.
But also, on the video, they shows each pack of cells he uses has individual over and underchange and temperature sensors, so the system is able to tell if any individual section is going bad. It's a pretty neat, and external installation, so I don't think it is very harmful on a "massive heat incident".