Actually looking into it a bit more to answer your question, I'm entirely confusing two different things. Mercury is tidally locked 3:2, it rotates 3 times for each 2 times it orbits -- but that is a result of history and not general-relativistic corrections, which are necessary to explain a different value (the precession of its orbit).
In fact our best understanding of why Mercury has the 3:2 relationship appears to be (if I'm reading these papers right) "because of historical reasons." That is, now that it's in that state, that state is stable and unlikely to decay to the 2:1 or 1:1 state, but getting into that state is much less clear and potentially requires that in the past, the other planets of the Solar system had nudged Mercury into a more eccentric orbit than it has now. The claim is that the eccentricity of that orbit caused the 3:2 resonance, then in more recent history these perturbations from other planets averaged out more to make Mercury's orbit less eccentric, but it still holds on to the resonance from its past.