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Feynman’s Derivation of the Schrödinger Equation

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Re: Feynman’s Derivation of the Schrödinger Equation

#31
This is goosebump material!

It is fascinating how concepts from classical mechanics port over into quantum mechanics. If we'd stuck with F=ma, perhaps we may not have gone far. However, the Hamiltonian and Lagrangian approaches are sweet ports.

Noether's theorem [1] connects symmetries of a lagrangian with corresponding conservation laws. Time translation symmetry implies energy conservation. Space translation symmetry implies momentum conservation in the direction of translation. This ports directly to QM. Feynman, in his lecture series, mentions another such symmetry - phase translation symmetry - that exists for QM actions and asks what conservation law does that correspond to. It is the conservation of charge. Mind blown!

[1]: https://en.wikipedia.org/wiki/Noether%27s_theorem

Re: Feynman’s Derivation of the Schrödinger Equation

#32
post #9
post #5

Where did we get that [Schrödinger's equation] from? It's not possible to derive it from anything you know. It came out of the mind of Schrödinger. -The Feynman Lectures on Physics For anyone who wants to study quantum mechanics and has a math background, I strongly recommend Shankar's quantum textbook. It has the most rigorous, clear, and correct derivations I have seen thus far, starting with vector spaces and movi…

For the love of God, do not use Shankar! The book is just down right atrocious. The fact that it became almost standard in American universities speaks more of the power of networking than anything else. Shankar's book is anything but rigorous, quite on the contrary. There are so many good QM books: For an absolute beginner I'd recommend David Griffiths Dirac's is very readable Sakurai's is very good though a bit adv…

Personally I love Shankar, and can't stand griffiths.

Re: Feynman’s Derivation of the Schrödinger Equation

#33
post #16

The Schrödinger equation was not derived , a more accurate word would be guessed . It's a fundamental law, like F = ma (although that is actually more of a definition than a law). There is no fundamental explanation why electrons obey the Schrödinger equation, just like there's no fundamental explanation why macroscopic objects obey F = ma.

It's actually not true to say that Schrodinger's equation, or F=ma, cannot be derived. This is because in order to derive something, you need to first start from a set of assumptions. You can pick any assumptions you want, that is your privilege, as it is mine. If you want F=ma to be an assumption, you can go on and derive things from that. But truly, F=ma is not the most general assumption in theoretical physics. If…

> It's actually not true to say that Schrodinger's equation, or F=ma, cannot be derived.

I don't think I said it couldn't be derived. I said there wasn't a "fundamental reason why the Schrödinger equation is X". Using Lagrangians to derive it then begs the question "but why must electrons obey the Lagrangian?".

> This is because in order to derive something, you need to first start from a set of assumptions. You can pick any assumptions you want, that is your privilege, as it is mine. If you want F=ma to be an assumption, you can go on and derive things from that.

Well, F = ma was a bad example, I grant you. It's actually a definition of what a force is, nothing more. But it's relevant, because it has a similar purpose (except in a different field of physics). A better example of a fundamental law would be action-reaction or something.

But yes, you're free to pick any assumption you like. But if you assume X, which came about because of assumption Y, it shouldn't be a shock that X can be used to derive Y. At that moment, they are just different notations for the same assumption. You might argue (and hell, I might even agree) that Lagrangians are so much more mathematically pleasing, so make a better assumption. But that doesn't change the fact that you're dressing up assumption Y as assumption X.

> But truly, F=ma is not the most general assumption in theoretical physics.

> If you look in any decent book on classical mechanics, you will find that F=ma in fact is derived from a much more general principle, the Lagrangian.

The Lagrangian is great for solving many problems. But it is definitely not more general than Newtonian mechanics. It can't deal with friction, or quite a few other non-conservative forces. On the plus side, solving oscillating systems is much easier. And it's so much nicer when not using Cartesian coordinates.

> That is the same Lagrangian that is the subject of the OP, which is used to derive the Schrodinger equation; and it's not just a coincidence.

While this is correct, Lagrangian mechanics refers to concepts such as energy which are defined from forces. In particular, Lagrangian's deal with systems with only conservative forces (but total energy may change with time). So it's really a circular argument to say "this concept can be derived from this even more abstract concept, which was actually defined from the first concept and at the end of the day is a guess."

There's nothing wrong with guessing fundamental laws. That's how the scientific method works, after all. You ask a question, guess the answer, predict what your guess would imply and test your predictions.

Re: Feynman’s Derivation of the Schrödinger Equation

#35
post #34

That's nothing: Feynman's proof of the Maxwell equations (FJ Dyson - Phys. Rev. A, 1989 ( http://signallake.com/innovation/DysonMaxwell041989.pdf) ) shows, that it is possible to derive Maxwells equations from Newtons second law of motion and the uncertainty principle.

Extra ) in your link.

Re: Feynman’s Derivation of the Schrödinger Equation

#36
post #9
post #5

Where did we get that [Schrödinger's equation] from? It's not possible to derive it from anything you know. It came out of the mind of Schrödinger. -The Feynman Lectures on Physics For anyone who wants to study quantum mechanics and has a math background, I strongly recommend Shankar's quantum textbook. It has the most rigorous, clear, and correct derivations I have seen thus far, starting with vector spaces and movi…

For the love of God, do not use Shankar! The book is just down right atrocious. The fact that it became almost standard in American universities speaks more of the power of networking than anything else. Shankar's book is anything but rigorous, quite on the contrary. There are so many good QM books: For an absolute beginner I'd recommend David Griffiths Dirac's is very readable Sakurai's is very good though a bit adv…

What in the world are you talking about? Griffiths is substantially worse than shankar.

Griffiths doesn't even get into Hilbert spaces until chapter three, at which point he delivers a broken and incomprehensible explanation. He attempts to teach Hilbert operators by analogy to the multiplication or application by adjacency people use in normal arithmetic. This is a terrible approach, and confuses the hell out of students who haven't already taken abstract algebra.

In what way is Shankar less rigorous than Griffiths?

Re: Feynman’s Derivation of the Schrödinger Equation

#37
post #33

Earlier quoted context omitted.

It's actually not true to say that Schrodinger's equation, or F=ma, cannot be derived. This is because in order to derive something, you need to first start from a set of assumptions. You can pick any assumptions you want, that is your privilege, as it is mine. If you want F=ma to be an assumption, you can go on and derive things from that. But truly, F=ma is not the most general assumption in theoretical physics. If…

> It's actually not true to say that Schrodinger's equation, or F=ma, cannot be derived. I don't think I said it couldn't be derived. I said there wasn't a "fundamental reason why the Schrödinger equation is X". Using Lagrangians to derive it then begs the question "but why must electrons obey the Lagrangian?". > This is because in order to derive something, you need to first start from a set of assumptions. You can…

> The Lagrangian is great for solving many problems. But it is definitely not more general than Newtonian mechanics

Sure it is. It's true that for certain systems, you can derive one from the other so in that sense they might be "just different notations" for the same physics (I'm disregarding non-conservative forces, which aren't really considered in fundamental physics). But the Lagrangian formalism really consists of two parts: Hamilton's principle and a choice (postulate/guess) of Lagrangian (or Lagrangian density). When we say that Lagrangian formalism is more general than Newtonian mechanics, it means we can describe physics using the Lagrangian which we can't get to via Newton's laws. For example, you would be hard-pressed to derive general relativity from Newton's laws, but if you start with the Einstein-Hilbert action, you can derive Einstein's field equations.

> A better example of a fundamental law would be action-reaction or something.

This is another example where the Lagrangian formalism is more general. In this case, a translation-invariant Lagrangian implies conservation of (canonical) momentum. But in more complex systems, Newton's third law might may fail when canonical momentum is still conserved (the prototypical example is the Lorentz force law).

> Using Lagrangians to derive it then begs the question "but why must electrons obey the Lagrangian?".

This isn't circular as much it is one less level of indirection. It's like if you say the reason a dropped object accelerates to the Earth is gravity, you have just shifted the question to "why must gravity behave as an inverse squared law". You can go further and say that Newtonian gravity is not fundamental, but is an approximation of from general relativity, where the dropped object isn't really accelerating. Again, the question is shifted to "why is general relativity described by the Einstein field equations". At each level of reduction you describe one phenomenon by something more fundamental. That you don't have a further explanation doesn't logically preclude that it's more fundamental.

Re: Feynman’s Derivation of the Schrödinger Equation

#38
post #33

Earlier quoted context omitted.

It's actually not true to say that Schrodinger's equation, or F=ma, cannot be derived. This is because in order to derive something, you need to first start from a set of assumptions. You can pick any assumptions you want, that is your privilege, as it is mine. If you want F=ma to be an assumption, you can go on and derive things from that. But truly, F=ma is not the most general assumption in theoretical physics. If…

> It's actually not true to say that Schrodinger's equation, or F=ma, cannot be derived. I don't think I said it couldn't be derived. I said there wasn't a "fundamental reason why the Schrödinger equation is X". Using Lagrangians to derive it then begs the question "but why must electrons obey the Lagrangian?". > This is because in order to derive something, you need to first start from a set of assumptions. You can…

> Well, F = ma was a bad example, I grant you. It's actually a definition of what a force is, nothing more.

Although I would agree that it's fair to say "F=ma is a definition of what a force is", I think of it more as a law of physics than as a definition.

I would also add that Newton's second law is more than merely the statement F=ma.

The original formulation is:

Law II: The alteration of motion is ever proportional to the motive force impress'd; and is made in the direction of the right line in which that force is impress'd. [1]

So in addition to stating what the word force means, the second law is also saying there are these things called forces which move things in a certain direction.

The way I think of F=ma personally, is that it means the laws of physics are associated with differential equations. So for me, the statement F=ma implies a huge number of other things, since without also having made the assumption that the laws of physics can be described in terms of vector calculus, the definition of force is rather useless and uninteresting.

[1] https://en.wikipedia.org/wiki/Newton%27s_laws_of_motion#Newt...

Re: Feynman’s Derivation of the Schrödinger Equation

#39
post #17
post #9

Earlier quoted context omitted.

For the love of God, do not use Shankar! The book is just down right atrocious. The fact that it became almost standard in American universities speaks more of the power of networking than anything else. Shankar's book is anything but rigorous, quite on the contrary. There are so many good QM books: For an absolute beginner I'd recommend David Griffiths Dirac's is very readable Sakurai's is very good though a bit adv…

It's been a long time now, but I pretty much agree with you. I really enjoyed Griffiths as an introduction but for reasons that escape me now I remember having a bad time with Shankar.

Griffiths is not great but for someone completely unfamiliar with the subject it will hold your hand quite nicely and is not pretentious at all.

For someone a little more knowledgeable it might get a bit boring...

Re: Feynman’s Derivation of the Schrödinger Equation

#40
post #4

This was written by a high school physics teacher. Very cool.

He was actually my high school physics teacher! And very good. A really cool guy and super smart.

whoa.. I think we were literally in the same class at Lab. Nice to see you here!
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