> It's actually not true to say that Schrodinger's equation, or F=ma, cannot be derived.
I don't think I said it couldn't be derived. I said there wasn't a "fundamental reason why the Schrödinger equation is X". Using Lagrangians to derive it then begs the question "but why must electrons obey the Lagrangian?".
> This is because in order to derive something, you need to first start from a set of assumptions. You can pick any assumptions you want, that is your privilege, as it is mine. If you want F=ma to be an assumption, you can go on and derive things from that.
Well, F = ma was a bad example, I grant you. It's actually a definition of what a force is, nothing more. But it's relevant, because it has a similar purpose (except in a different field of physics). A better example of a fundamental law would be action-reaction or something.
But yes, you're free to pick any assumption you like. But if you assume X, which came about because of assumption Y, it shouldn't be a shock that X can be used to derive Y. At that moment, they are just different notations for the same assumption. You might argue (and hell, I might even agree) that Lagrangians are so much more mathematically pleasing, so make a better assumption. But that doesn't change the fact that you're dressing up assumption Y as assumption X.
> But truly, F=ma is not the most general assumption in theoretical physics.
> If you look in any decent book on classical mechanics, you will find that F=ma in fact is derived from a much more general principle, the Lagrangian.
The Lagrangian is great for solving many problems. But it is definitely not more general than Newtonian mechanics. It can't deal with friction, or quite a few other non-conservative forces. On the plus side, solving oscillating systems is much easier. And it's so much nicer when not using Cartesian coordinates.
> That is the same Lagrangian that is the subject of the OP, which is used to derive the Schrodinger equation; and it's not just a coincidence.
While this is correct, Lagrangian mechanics refers to concepts such as energy which are defined from forces. In particular, Lagrangian's deal with systems with only conservative forces (but total energy may change with time). So it's really a circular argument to say "this concept can be derived from this even more abstract concept, which was actually defined from the first concept and at the end of the day is a guess."
There's nothing wrong with guessing fundamental laws. That's how the scientific method works, after all. You ask a question, guess the answer, predict what your guess would imply and test your predictions.