He must mean longest. This chart[0] shows that the Ohio is by far the largest tributary of the Mississippi by volumetric flow, and also shows the Atchafalaya bifurcation. However, the wiki articles for the Missouri[1] and Ohio[2] show average discharges into the Mississippi of 87,520 cu ft/s and 281,000 cu ft/s, respectively. Not as great a difference as the first chart [0] shows, but still significantly different. Even more interesting, since the Missouri drainage basin is about 2.5x larger.
[0]https://en.wikipedia.org/wiki/Mississippi_River#/media/File:...