If you're going to be pedantic, do it right.
The average of 0 and 2π is π, so an average can certainly be π. Yes, the average of a finite number of rational numbers cannot be π since π is irrational. But why would the sinuosity of any river be rational? The sinuosity of a circle is exactly π, for example. The true sinuosity of any given river is almost certainly irrational as well, since irrational numbers vastly outnumber rational ones in a very relevant sense: if you pick a real number uniformly at random between 0 and 1, there is literally zero chance that you will pick a rational number. Similarly, there is zero chance that the sinuosity of any river will be π or that the average of any finite number of rivers will be π. However, what they mean when they say this is this more precise fact: if there were an infinite number of rivers formed like those on Earth, the average sinuosity of that infinite collection of rivers would be exactly π.
There. That's how to be pedantic.