Earlier quoted context omitted.
Don't use boiling water with hot water bottles; the ones you can buy have warnings about this (it can damage them). Just use hot water from the tap (which hopefully should be more efficiently heated than however you boil water as well). Don't worry about energy consumption; it's negligible for the hot water bottle, and for the electric blanket as well, especially compared to keeping your house heat up high at night.…
If the bottles are dedicated to this use, it's fine. The soft-walled ones may discolour slightly.
I put boiling water into a fairly thin-walled rubber one, and it sprang a leak a few minutes later, so I'm more careful now.