I've also had luck with some other niche community sites such as Designer News. The important piece here is to try and integrate yourself into the community instead of just spamming them with links to your website. Get involved in conversations about things other than your start-up (people notice this and appreciate it). Make friends with the moderators. When Designer News was still private with no search capabilities I wrote a quick search engine built on sphinx to index all of the posts and make them searchable. Not only did this get me an invite to the community but also sent some nice traffic to my start-ups site via a small link on the search page.
I've had little to no success with twitter and facebook, although I might be doing it wrong. Some of the targeted communities that you can find through google plus look somewhat promising, but I've yet to fully explore these.
Our most vocal power users are people we know personally, or met at local events (our local co-working space).