As a development lead, we recently abandoned our plans to migrate to Python 3. Here's a short summary of why:
To begin the migration, we needed to move from Python 2.6 (which is the default on our CentOS6 production boxes) to Python 2.7. This transition is actually rather hard. We can't use the packages provided in CentOS base or EPEL, because they are all complied against Python 2.6. To re-produce all of our package requirements would require us to either build new packages of the compiled libraries (such as MySQL-python, python-crypto, PyYAML, etc), or load down our production environment with a compiler and all of the development libraries.
Migrating from Python 2.7 to Python 3 would have required a nearly identical effort (there's not a lot of Python 3 packages for CentOS, in particular the packages that we need for our application).
Frankly, it's just not worth that effort at this time. Python 2.6 is the default environment, there's solid package support for it, and it just plain works. We'll make that dive when Python 3 becomes the default for CentOS (scheduled for 8 or 9, IIRC), and probably not before.