1) Chrome(and some plugins) pin's certificates and would notice a man in the middle attack(unless it was done with google's key). Sure, most corporate targets probably use IE, but if anyone uses chrome on or one of these plugins on the network, you've both alerted your target and exposed a presumably tightly guarded ability. Hell, if it get's reported, you've probably burned the ability. Of course, you might be able to filter out both the plugins and chrome, but it's a risk.
2) NSA could legitimately just ask for the company's emails from Google. Petrobras is a Brazilian company in Brazil staffed by Brazilians and as such a legally allowed target for Foreign Surveillance without either the NSA's twisted definitions of search and who is a US national. Google is legally required to hand over the information by the Foreign Intelligence Surveillance Amendment Act of 2008. Why authorize an operation that could reveal both the CA's you have in your pocket and you network penetration exploits?
As a side note, the cited slide looks nothing like anything else we have seen and lack security/ handling information (e.g the prominent TS/SCI/ORCON/NOFORN on the top of the prism slides).