Earlier quoted context omitted.
The issue here is that EVs tend to be charged when the sun is down. When sun is up you tend to be at work or driving. The surplus power is coming from solar.
EVs are parked 95% of the time. If it's parked, it can be charged. Work places also have electricity.
Only households can access the free electricity window. If you're not on a free plan you can get reduced rates during the solar peak window but business accounts aren't allowed to access those either.