For those not familiar, the secret ingredients are to do with the Lime Cycle [1]: 1) Quicklime/Slakedlime (Calcium Oxide, CaO) 2) Lime (Calcium Hydroxide, CaOH2) 3) Limestone (Calcium Carbonate, CaCO3) To keep it simple, typically you start with Quicklime (CaO) and after construction you end up with some mix of all three and after hundreds of years, the masonry transitions to mostly Limestone with microscopic traces…
>Cement/Concrete (based on Portland cement) is water proof That's patently untrue. Otherwise we wouldn't need concrete sealants.
I'm not sure why I remember cement to be water proof. Its possible I infered from how its been used around me. I have seen cement very often used where water contact is expected (bathrooms etc). I have also seen brick walls plastered with an extra layer of cement as putty considered to be rain proof and any leaks were thought of as poor workmanship rather than poor material choice.
P.S. I'm not a builder. I've taken an interest in the topic a few months ago.