While I believe a significant portion of audiophile gear is unscientific nonsense, in this case it’s not clear how adding different materials into the circuit would add distortion or change the audio in any way.
If nothing else it shows those high end $1,000+ cables they buy are nothing but placebo effect.
In other words, they got fooled.
What’s happened in electronics is that there’s a cutoff, above which the audio quality doesn’t get any better, but that cutoff is much lower than anybody can believe. So the psychological cutoff is higher than the physical one, and a role of marketing is to raise that cutoff even further.