Earlier quoted context omitted.
The problem temperature is 260°C which can easily be avoided by not heating an empty pan (oil/liquids will distribute the heat more evenly) and you'd be unlikely to want to cook at that kind of temperature.
Teflon is not very thermally conductive, so the bottom contacting the metal substrate may be at a significantly higher temperature than the top. Chemistry reactions have activation energies, and you can generally always trade temperature for time. If it happens in a minute at 260 C, it will still happen at 200 C, just slower.
I don't think that's particularly accurate unless you're considering the action of individual atoms. e.g. Water is considered to boil at 100°C but there will be some water evaporating at lower temperatures but this is a different process that only occurs at the surface. I don't think it's accurate to say that water is "slowly boiling" at low temperatures unless you're reducing atmospheric pressure.