Earlier quoted context omitted.
> Particles have a defined position and momentum Which we don’t know precisely. Entropy is about not knowing. > If you somehow learned these then the shannon entropy is zero. Minus infinity. Entropy in classical statistical mechanics is proportional to the logarithm of the volume in phase space. (You need an appropriate extension of Shannon’s entropy to continuous distributions.) > So now you are forced to consider e…
> Which we don’t know precisely. Entropy is about not knowing. No, it is not about not knowing. This is an instance of the intuition from Shannon’s entropy does not translate to statistical Physics. It is about the number of possible microstates, which is completely different. In Physics, entropy is a property of a bit of matter, it is not related to the observer or their knowledge. We can measure the enthalpy change…
Enthalpy is also dependent on your choice of state variables, which is in turn dictated by which observables you want to make predictions about: whether two microstates are distinguishable, and thus whether the part of the same macrostate, depends on the tools you have for distinguishing them.