See, the valley can exist because humans stay the same, at least to our brains. We don't madly change form or shape every 20 years. But user interfaces do. So how do our brains know a web interface looks too much like a desktop interface? It can only know because we know what both are "supposed" to look like.
But kids being brought up on web interfaces that look like desktops will not have a valley because to them that looks normal. There is no set "desktop" look or web interface "look." Its only what we've created. Create something different, and the valley will go away.