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Light can make water evaporate without heat

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71–80 of 198 posts

Re: Light can make water evaporate without heat

#71
> The researchers found that the effect varied with color and peaked at a particular wavelength of green light.

I wonder if this affects photosynthesis in any way? IIRC plants are green because chlorophyll does not absorb that color. Maybe that’s partially because green light induces too much evaporation?

Re: Light can make water evaporate without heat

#73
This is being misinterpreted here. They have found an unknown mechanism where water is absorbing light it would not absorb otherwise while in the boundary layer of a hydrogel and thus evaporating faster than it would if simply heated.

If not a mistake or some unsustainable side reaction, this could mean cheaper things that require evaporation like desalination.

A lot of people here though are saying it means things which would violate conservation of energy.

Re: Light can make water evaporate without heat

#74
post #44
post #17

I can't wrap my head around this story. What does it mean in thermodynamic terms? Isn't there a fixed amount of energy per mass that it takes to convert liquid water into vapor? Why does it matter that the energy comes from light?

Thermodynamics and evaporation are my day job and I think most other explanations here are missing the point. Evaporation normally occurs when individual water molecules have enough thermal energy to break their intermolecular bonds, leaving the bulk liquid and entering the air. In this case, they found strong evidence that water molecules were being removed in groups of several water molecules. Because intermolecula…

Worth noting that I’m going off the preprint since I don’t have PNAS access.

https://arxiv.org/pdf/2201.10385.pdf

Re: Light can make water evaporate without heat

#75
post #44

Earlier quoted context omitted.

Thermodynamics and evaporation are my day job and I think most other explanations here are missing the point. Evaporation normally occurs when individual water molecules have enough thermal energy to break their intermolecular bonds, leaving the bulk liquid and entering the air. In this case, they found strong evidence that water molecules were being removed in groups of several water molecules. Because intermolecula…

But in a closed system, the energy to boil or evaporate the same amount of water is the same right? As in, you still have to pay the energy price but evaporating all the water is probably easier engineering wise?

Speaking as an person ignorant of this entire field, it seems to me that if it's the case that groups of molecules are breaking off rather than individual ones, the total energy required would be less.

But it's comparing apples to oranges, because the "end product" is different. In one, you have a cloud of individual molecules. In the other, you have a cloud of molecule "clumps". If you take it further and break those clumps down to individual molecules as well, I expect the total energy input would match that of evaporating water in the normal way.

To the experts reading this, am I close?

Re: Light can make water evaporate without heat

#77
post #17

I can't wrap my head around this story. What does it mean in thermodynamic terms? Isn't there a fixed amount of energy per mass that it takes to convert liquid water into vapor? Why does it matter that the energy comes from light?

> What does it mean in thermodynamic terms? Isn't there a fixed amount of energy per mass that it takes to convert liquid water into vapor? Yes. The rest of the energy comes from the bulk water/hydrogel in other words, the bulk water is cooled by this process. What’s happening is that energy is sloshing around between various degrees of freedom of the system (the temperature of the system is not zero). When it sloshe…

You don't need monochromatic green light - that was just the test condition to find the best wavelength. Broad spectrum sunlight should do the trick.

Re: Light can make water evaporate without heat

#78
post #50
post #27

Earlier quoted context omitted.

My 8th grade understanding is evaporation doesn't always mean steam.

What exactly is the distinction between water vapor and steam?

Where I'm sitting now, the humidity in the air is about 40%. Would you consider that to be "steam"? I feel like steam generally needs to be hot, or at least somewhat warm. Cold steam exists, but is specifically called out as an exception to the rule. Maybe steam needs to be somewhat translucent?

Re: Light can make water evaporate without heat

#79
post #50
post #27

Earlier quoted context omitted.

My 8th grade understanding is evaporation doesn't always mean steam.

What exactly is the distinction between water vapor and steam?

Isn’t steam just water vapour off boiling water? I.e., water vapour which, on condensing, yields heat to the surface on which it condenses. Steam is hot water vapour, IOW.

Re: Light can make water evaporate without heat

#80
post #44
post #17

I can't wrap my head around this story. What does it mean in thermodynamic terms? Isn't there a fixed amount of energy per mass that it takes to convert liquid water into vapor? Why does it matter that the energy comes from light?

Thermodynamics and evaporation are my day job and I think most other explanations here are missing the point. Evaporation normally occurs when individual water molecules have enough thermal energy to break their intermolecular bonds, leaving the bulk liquid and entering the air. In this case, they found strong evidence that water molecules were being removed in groups of several water molecules. Because intermolecula…

> I'm not really sure whether to even call it evaporation

I can't help but think of ultrasonic humidifiers/misters, which use vibration to do evaporation-adjacent kinds of things.

I also wonder if specific wavelengths of light are involved (sort of how 2.4ghz microwaves work on water)

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