I have hardly seen any shop so far, at least in the most big/medium corporates who use Python or Ruby heavily in scripting. Its either bash or Perl. The problem is as I said, Neither Ruby or Python were every marketed, designed or even took off as a Scripting languages. Most start ups pick up Python/Ruby basically because they don't need a new language with their existing Django/Rails code base.
Even in such cases one you infrastructure begins to expand, one you are a reasonably sized team. Perl usage becomes inevitable.
Even among the heavy Python using companies like Google, its becoming clear why anybody would not use Python or even deprecate it in production. Because it doesn't quite really have a strong dedicated niche. Php has the web, Perl has the scripting/glue part on the Unix environment. Java has the static large app part.
Python/Ruby have great web development frameworks.But when it comes to scripting, there are no real alternatives to Perl. And besides if you wish to develop large applications, Static languages serve well. There is no point in using Python when you don't want to cook things quickly.
You will be shocked how many places apart from web communities and forums like these people haven't even heard of Ruby and Python. Most of my friends in big companies some of who also lead big teams over the years 'have just had a look at Python'.
I realize that I have posted this in a community that likes Python a lot and I'm likely to be downvoted. But I'm writing just what I've seen over time.