My feeling after reading the article is that he's link-baiting to make a valid point about trends in education in general. He gets demerits for the misdirection, but his fundamental question is essential and needs to be engaged.
Is he correct that education is fundamentally a human, not technological, endeavor? Is something essential lost when teaching is made completely abstract by software and engineering?
I say this as a home-schooling father of five that uses a lot of technology -- DVDs, online -- to augment our curriculum, and couldn't be happier that I'll be able to have my kids go through MIT, Stanford, Khan, etc., online content, and I think our options in the next few years will be even more amazing.
I'm in agreement with the author that human interaction has to be fundamental to the educational process, but technology must play a role. Books themselves represent arguably the most important mass application of technology in modern history.
So the question for me is: does Khan (or Mathalicious for that matter) attempt to become a replacement for human interaction in education? I don't think so. That is still left to the freedom of any parent or teacher using the material. If more context needs to be applied to a given technology-driven lesson, then the parent or teacher is certainly not prevented from doing so.
The more I think about it, the more I think the author is simply advocating one abstract technological solution over another: his particular brand of context-driven content vs. Khan's more conventional content. Nowhere is the question of actual human interaction broached, just the question of whether qualified "experts" created the content to begin with. He may be correct that his content on the whole is better than Khan's, but his invocation of the "human vs. technological" seems to me yet another misdirection.
The real human element of education takes place in one-on-one situations, with a teacher or parent who can intuit where the child's understanding is at, respond in real-time to the student's own reactions, and change their approach in real-time accordingly. Nothing can replace the give-and-take of face-to-face teaching. Every student is different and real teachers know how to change their tactics slightly, drastically or somewhere in-between to help a student make that crucial conceptual breakthrough.
So to me, "Mathalicious vs. Khan" is merely pitting one abstract set of materials vs. another, and has nothing to do with "human vs. technology." I may use one of them or both or neither, but I won't give up my direct interaction with the student, and, having been raised by a teacher myself, I know that real teachers understand this as well.