I think Python's a great language to start with, maybe. What turned me on to PHP and web programming is that I could do things easily and get visual results back. Flask is a better way to build server side apps than raw PHP, but it hides a lot and a significant part of the Python language needs to be understood to understand a lot of it.
I spent a year learning about website design shortly after turning 14 and during that time eventually came across PHP. For about another year until 10th grade started, I kept doing simple PHP sites. I had looked at Python once and felt kind of offended by it, and I didn't understand OOP. "Why do I have to do mystr.split(' ') instead of explode(' ', $mystr)?" "Why don't variables have sigils?" "What's this import crap?" "Why do I have to have indentation?" (I commonly didn't indent my PHP code during this time.) I also used Windows. I still hate cmd.exe.
I took the AP CS course in 10th grade, and Java forced me to at least partially understand OOP and why it may be useful or cool. (We also did everything on a Mandrake Linux computer.) I looked at Python again about midway through the year and started loving it (I was in the habit of indenting with one space at that point since the teacher required at least some indentation so Python's forced indentation didn't bug me anymore). After several months in Python I began to understand that real OOP went far beyond what Java supported. Now that I'm 21 Python is still my favorite language, but I do really like Clojure.
So I still think Python is a perfect beginner's language, but I'm not entirely convinced that Python as Python is enough to spark an interest to go do your own thing. The first thing I reached for when I learned Python well enough to do anything was video game programming. Making interactive applications that aren't limited to the terminal held my interest a lot more back then.
(My CS teacher also resolved many difficulties with the = sign by always reading code like "a = b" as "a gets b". Some people have trouble enough with homonyms in language, seeing the '=' mean something completely different to what they've been used to for 10 years can be startling.)