We can't see down to 0 seconds, because very soon after the big bang, the universe was filled with dense, extremely hot, opaque plasma. The closest we can get is the "recombination epoch" [0], which is roughly 370 000 years after the big bang, when, because of universal expansion, the plasma got cold enough for neutral hydrogen to start forming, at which point the universe became transparent.
As protons gain electrons in high temperatures, they don't form in the ground state. Instead, the newly minted hydrogen atoms are in a highly exited state. As they fall back to their ground states, they emit infrared photons at ~3000K color temperature. These photons, redshifted by the expansion of the universe to ~2.7K, are the Cosmic Microwave Background, the uniform ultimate backdrop we have when looking in any direction.
[0]: Which has it's slightly incorrect name (should not have re-) because it was named before the big bang became a widely accepted or known theory.