Cement is a substance used for producing mortar and concrete. It's never used on its own. It is a "binding agent". Note that the term "cement" is often not used correctly in everyday speech, with people talking about gluing bricks together with cement, when bricks are actually glued together with mortar.
Mortar is the glue between bricks. You can see it between the bricks in any brick wall. It is produced by mixing cement with sand. This results in a paste which hardens after being applied to a brick.
Concrete is a substance that can be put into any shape, and then hardens. The bricks in a brick wall can be made from it. (More examples?) It is produced by mixing cement with sand and gravel (which are larger rocks).
There is also reinforced concrete, which the Romans didn't have. While concrete by itself can in principle be moulded into any shape, this can sometimes fall apart after hardening. Reinforcement refers to putting the concrete around metal wiring, which allows for more versatile shapes while maintaining stability.
Feel free to provide corrections.