For the record, Khan Academy is going to eventually scrap all the Python videos. John Resig, creator of jQuery, is going to redo all the videos narrated by him and with the code written in JavaScript.
JS doesn't sound like a wise choice to me.
I'd say stick with something a bit simpler, especially given that it's Khan Academy, not Stanford, so it's likely to attract far more casual lay-users who just want to know "a little bit about programming." The casual nature of the engagement means there is probably a very low threshold for quitting if the program is resulting in more confusion/frustration than "aha moments."
I think it's great they're doing it, tho! More people should learn "a little bit about programming."