Since 90% of the cost is probably in R+D of the telescope, one could build and deploy another for another 10%. Why isn't this done? Why is every space telescope completely unique?
Because it's a wrong assumption. Significant cost come from the assembly and testing of all the components itself, that you would have to redo entirely. Also if you were to build just 2 or 3 of them, you can't expect any economy of scale. On top of that, the operational cost of JWST is expected to be around 1B$ for it's lifetime, you could expect that to be similar for every single replica you have. And finally, you…
If you look at the line items on a build, you might see something like a $200 bolt. It’s not that there was $198 of R&D going into the design of the bolt, it’s that quality management drives the cost. Chain-of-custody, bonding, material testing, witnessing etc. are all part of that effort and they don’t scale like a design spec does.