So like, if you don't deliver those shipping containers of hot sauce, I just click the "I was scammed" checkbox on my smart contract dashboard?
Where exactly does the leverage of smart contracts come into play?
The biggest reason libertarianism is a nonstarter is that it outright rejects the state monopoly on violence. Without a lone arbiter, societies fragment due to intragroup competition and violence. As a society fragments, the size of the monolithic projects it can engage in become smaller and smaller.
International trade is already so fragile that a stuck tanker threatens swaths of the entire thing. Now picture how infinitely improbable a system like that is if there's no physical enforcement mechanisms backing contracts up.