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And abundant CO2 means oxygen is abundant.Oxygen combined with other atoms is not rare. From https://en.wikipedia.org/wiki/Composition_of_Mars
> Based on these data sources, scientists think that the most abundant chemical elements in the Martian crust are silicon, oxygen, iron, magnesium, aluminum, calcium, and potassium.
The problem is separating the Oxygen from the other materials to get Oxygen molecules that you can breath, and that requires a lot of energy.
Last year some team made a project to produce Oxygen molecules in Mars using the soil and energy, with some method similar to https://en.wikipedia.org/wiki/Aluminium#Hall%E2%80%93H%C3%A9... (Here the process use Carbon rods as cathodes, that get "burned", but IIRC their idea was to avoid the Carbon rods and collect the Oxygen molecules.) I'm not sure if this early prototype is viable, anyway.
Also, extracting the Oxygen molecules from CO2 requires also a lot of energy. Plants need a lot of sunlight to do that and the artificial methods also need a lot of energy.