So, what is violet actually? WIkipedia says both that it's blue near end of visible spectrum, and then adds that it's mix of blue and red with more blue than red. Those both seem contradictory. AFAIK human eye doesn't differentiate between wavelenghts of blue, it just compares intensity of whatever triggers its blue cones to whatever triggers its red/green cones, no? Or, maybe it's the fact that some ranges of ultrav…
As I understand it, the cone cells in your retina responsible for "red" have a second peak on the violet-side of blue. This means that a violet wavelength will get efficiently absorbed by both the "blue" and "red" receptors but not the "green" receptors. That sort of creates a "periodic boundary condition" to colour perception, wrapping a monotonic wavelength spectrum into a colour wheel.
When I set my LED lights to RGB(0.1,0,1), it looks very much like my blacklights (UV LED, or 405nm lasers. and maybe I should get a tube to compare). I can tell them apart because the physical offset of the R and B LEDs makes a bit of visible fringing, or maybe it's that the single violet photons are coherent (with themselves) whereas the red and blue photons are not, or maybe the retina is a subtler instrument than its simple physical description suggests.