Earlier quoted context omitted.
I would only have thought of MySQL.
MySQL isn't a general solution to problems of scale, because you don't know what problems you're going to have until you have them. So for example if your scaling problem is ACID compliant database updates - say you're the next fintech - then I was under the impression that MySQL would be the last database you'd want to be using. Have I missed something?
Overall, MySQL and Postgres are great Open Source databases, but MySQL has the edge for enterprise features (ie. replication options) and a simpler grant system.
Source: DBA.