The LLV's are not merely old, they're
ancient. The EV marketplace still isn't particularly mature: there are competing charging networks, the charging standards are still evolving, and in the US, there are perhaps two mainstream manufacturers of pure BEVs (Tesla and Nissan).
If you're the sort of customer who keeps a vehicle 3 years and then upgrades, none of this is likely a worry for you. Any shakeup in the charging networks or incompatible changes to the standards will probably happen long after you sell the car.
The USPS, on the other hand is in this for the long haul. It seems reasonable to suppose that they'll have their own charging network, so problem solved, right? Wrong. They'll still need parts support every part of this operation for at least 35 years if they keep them as long as the LLVs.
Remember the lengths one dedicated person had to go to to resurrect the DE-19 connector[0]. You're looking at that problem multiplied by thousands of parts.
I've always coveted the original Honda Insight (the two seater), and one popped up for sale near me last year so I did some research. First party support is pretty well done. Third party support exists, but it's not a volume business, and it's priced accordingly. And that's a car that's only 15 years old.
The mail truck fleet will be bigger, but the price of parts will still be high if there are big shifts in the market and nobody's making anything similar. The market has matured and stabilized since Honda quit making the original Insight, but probably not enough to inexpensively support a vehicle for 3 decades.
[0] https://www.bigmessowires.com/2016/06/04/db-19-resurrecting-...