The most interesting national electricity grid has to be Japan's, with two completely different networks operating at different frequencies, and connected by HVDC. https://en.wikipedia.org/wiki/Electricity_sector_in_Japan
That's a tiny amount for an industrialised nation of 125 million people, considering that the border between the grids cuts right between Tokyo and the other western centres of population.
I think this, and the nuclear power shutdown, lend some context to Japan’s push for a hydrogen economy.