Colonize the moon first: 1. plenty of solar power 2. close to earth 3. easy to launch out of its gravity well 4. lunar base technology can be iterated far more rapidly
If you think about it we could be doing so many cool things as species, if only we clean up the whole politicking and squabbling over resources and power.
Technologically it seems we are on the edge of being able to expand out into solar system.