OK, I see. First of all thanks a lot for this link. Fantastic website!
I genuinely had no idea the delta-v of so many asteroids was so small, compared to LEO. It fills me with 'educated hope', in regards to not-too-distant (in time) sustainable space industry — this and many other factors.
Regarding Isaac Arthur (I'd link the video, but there's so many), he definitely doesn't make that kind of rookie mistake, so I assume it's more of a tongue-in-cheek remark, to address popular concerns and show solutions — drive the point that a space-faring civilization is equipped to deal with such 'problems'.
About rare-Sun materials, I was more implying the possibility of finding isotopes or elements scarce in the belt and inner solar system — but you're right, even just the outer system is already full of useful stuff.
You've convinced me that it does seem pretty improbable that we'd get such a good near-earth candidate during the short window of time when it would really help us a lot, though, assuming we don't take another millennia to get out there (and even then).
Just curious, at the current pace (considering 1950-today) and barring any major stall/setback/boost (no WW3 etc), what would be your personal estimate for the first profitable mining operations? 10, 30, 100 years?