Earlier quoted context omitted.
Please correct me if I’m wrong but no RaspPi has a PCIe interface, yet. From the embedded side of things, I would expect that to be a whole Pi generation out. Even then, I’m honestly not sure what the use case is, the Pi is doing amazing things with SPI and USB.
The RPi 4 uses PCIe to interface with the USB 3 controller. However it doesn't provide an external interface for it.
http://mloduchowski.com/en/blog/raspberry-pi-4-b-pci-express...