Make a vacuum onion.
1d-compressium, 1d-tensilium, and 2d-tensilium are all allotropes of obtainium, being the materials with the highest uniaxial compressive strength to mass ratio, the highest uniaxial tensile strength to mass ratio, and the highest biaxial tensile/shear strength to mass ratio. Currently, those are probably diamond struts, buckytube fiber cables, and graphene sheets.
Throw 2d-tensilium envelope around a tensegrity frame with 1d-compressium struts and 1d-tensilium cables. Pump out the interior gas until it breaches or collapses.
Start over. This time, put another frame and envelope around the first, and anchor them to each other with more 1d-tensilium cables. Pump out the interior gas of both pockets until the outer shell breaches or collapses.
Repeat, until the pressure differential on every envelope and shell is insufficient to breach the envelope or buckle the frame. Now you have a gradient from vacuum to atmospheric pressure instead of a perfect vacuum in the whole volume, but you don't have to find any unobtainium to build it.
As a bonus, you can put the envelope on the inside of the shells, and follow a similar process of breaking each one with air, to make an inflatable spacecraft hull that can hold 1 atm of breathing gas on the inside without rupturing in vacuum, using minimal mass.