The vomit-comet ICBM video? I'm a big fan of SpaceX, but I think they'll get to Mars before governments on Earth allow that concept to happen.
Your passengers do multiple g's to altitude, then go weightless, then go back to taking g-forces on descent. That's the vomit part. Not a great customer experience.
Meanwhile, the Starship looks like an ICBM to every early warning radar on the planet. It's only during reentry that it stops looking like an ICBM, but most missile defense strategies call for intervention in the boost phase.
Let's suppose that they address those false positive detection issues. If you're a military planner, though, you're probably asking yourself how many MIRV warheads could fit inside a militarized Starship retrofitted for a preemptive strike?