> I know the US Government oversaw the Google IPO and the stocks weren't printed out of thin air.
But... the stock did get printed out of thin air. When Google was originally being started — like any startup — the founders could have, and regularly did, make stock appear out of thin air. For example, that's what dilution is. If you've ever worked at a pre-IPO company that's raised money from VCs, at some point your company likely printed stock out of nothing, diluting your share of the company however much they liked — and there's not much you can do about it.
In fact, all of the stock sold in the Google IPO was at one time printed out of thin air. That's where stock comes from. When Larry and Sergei and their lawyers (and whoever) drew up the initial documents when they were incorporating Google, they decided there would be X shares, and then over the course of many years increased that number semi-arbitrarily as they saw fit to sell to VCs, and eventually to sell to the public. All of the stock was made up, and it was distributed mostly to the founders and the early investors, just like any startup. They weren't being particularly evil or unfair, that's just how startups work.
In fact, the Google board could, today, legally decide to invent more Google stock out of nothing and sell it, or give it away. Here's some good reading on Investopedia about dilution and stock issuance, along with a recent example of a company legally creating stock out of thin air and giving it to their new CEO, diluting existing shareholders: https://www.investopedia.com/terms/d/dilution.asp
Ether had a one-time initial sale, and everything since is Proof of Work. In terms of being certain that Ether isn't being printed out of thin air, it's IMO quite a bit more trustworthy.
(And if you want to really get down into the details, printing money out of thin air is a daily occurrence with the US government: that's how inflation works. We make dollars out of nothing. For good reason, but still!)