Earlier quoted context omitted.
Under what circumstances does one need to have in order to make them combine into water, organically? (Meaning without any device or machine, assume you have two big clouds of each element floating in space - if they collide, do the naturally just form into water molecules?)
At reasonable temperatures, yes, the clouds turn into water and release energy, hydrogen burns. Water is entropically preferred as a lower energy state than separate atoms/molecules because of lower enthalpy at reasonable temperatures. Depending on density and ignition sources the reaction rate may vary, but it doesn't have to explode in a ms when there is a billion years available.
I think the concept you're thinking of is free energy, which determines the final destination of a process. The equation relating these things is (change in free energy) = (change in energy) - temperature × (change in entropy). Entropy only becomes the dominant component when temperature is high. And, as expected, water molecules dissociate at high temperature.