Earlier quoted context omitted.
High voltage, sure, but outside of an inverter that you can/should buy prepackaged none of this needs to be high voltage. The system in the embedded video has 14 sets of cells in series, meaning 40-60 volts.
Danger of electrocution is not particularly high, but can easy start a serious fire with such batteries. The energy capacity with create a seriously hot arc if shorted, and there is a potential for thermal runaway of the battery cells.
Luckily he avoided the acid spray, but he had to empty 4 large fire extinguishers from the nearby boats to put out the fire and cool down the remains of the batteries enough so they did not immediately catch fire again.
I have a huge respect for what a huge solar array and a big bank of batteries can do after seeing what a relatively puny battery could actually do.
A standard AC system can't deliver even a percentage of that current.