Photo sync on iOS without iCloud is a huge pain atm.
My backup strategy involves a NAS folder that stays up to date (i.e. also deletes photos that I delete on my phone), and which I occasionally sort into final location. After that I can free the space on my phone.
All other options (including Resilio Sync) are a add-only "sync"[1], which makes it annoying to sift through all the photos including those I already weeded out a week ago.
[0] https://docs.syncthing.net/users/faq.html#why-is-there-no-io...
[1] In theory, Resilio has a real sync, but for some reason, not for the iOS camera roll.