I am a Mozilla supporter and FF is my "daily driver" browser. Very interested in this feature. Chrome has had it for a years, and it's a killer feature for many developers. It's very very useful to have multiple browser windows open, each logged into the same site as a different user. A lot of people do this by opening multiple browsers (FF, Chrome, Edge, Safari, etc) but that has its limits and it just adds another…
Edit: I guess I'm misremembering how Chrome works, or maybe they changed it since I've last used Chrome seriously. I'll leave the comment so the replies make sense. Original comment: I'm kind of surprised that Mozilla went with a per-tab approach here, since they went with per-window for private browsing (while Chrome did the opposite: per-tab private browsing and per-window profiles).
So Firefox seems to be just jumping ahead of that initial limitation from the start here.