> And what if there is a micro-scale reversal of entropy, as I previously mentioned? Let's say a collision of two electrons, or an electron with a surrounding gas molecule, that results in a sudden increase in orbital energy of an electron (plus another particle losing all its energy of course). Vanishingly unlikely of course, but with an uncountable number of collisions occurring every instant it will occur somewhere, sometime.
Sorry, I'm not sure what you mean by this.
> You say that it's "observable" with single-particle experiments. Are you sure you've performed enough of those experiments to unconditionally guarantee that such situations will never under any circumstances occur?
I said (in the other reply) it's observable "to the best of our measuring ability" (repetitions, and energy), precisely because we'll never reach 100% certainty.
But your wrong claim wasn't "things that we don't know yet might be happening", rather "all particle interactions imaginable are happening all the time, just with a small probability". The former is tautologically true. The latter is just pseudoscience, as it is:
1. Unfalsifiable: the more we keep measuring that only some interactions happen in Nature, the further you'd just push that small probability.
2. Without predictive power.
It's not like superseding Newton's laws of motion with GR. It's like saying "beyond the speeds and masses we've observed, objects are free from any laws of motion whatsoever". And furthermore adding that it can be proved.
And that's only for laws like conservation of quark and lepton numbers. For conservation of energy and momentum, the prohibition is much stronger: Noether proved mathematically that they're another way of saying the laws of Nature are the same today than yesterday, and the same here than a meter away. Claiming they're being broken all the time is the same as saying the laws of physics are different all over the place, and from one moment to the next. The slightest evidence or proof of something of the sort, and we pretty much start all physics from scratch :)