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Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

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Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#31
post #22

So it's 20x cheaper than the noble gas version — what's the absolute cost? I assume it's not cheaper than pumping fossil fuels yet, but I'm curious to know how far away it is.

Yeah, this sentence in the middle of the article:

> The ability to turn CO2 into fuel at a cost comparable to a gallon of gasoline would render fossil fuels obsolete.

Doesn't actually say that this is at a cost comparable to a gallon of gasoline :)

Sly words.

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#32
post #19

Earlier quoted context omitted.

No, that's not likely to happen. Photosynthesis is pretty inefficient, typical plants have a radiant energy to chemical energy conversion efficiency between 0.1% and 2%. Most commercially available solar panels have more than 10 times this efficiency.[1] [1] http://physics.stackexchange.com/questions/109739/is-plant-p...

Sure, but I bet your solar panels don't manufacture and maintain themselves. To the GP's point, the total cost of ownership of a plant that makes gasoline-level fuel is going to be more about water and land than anything else. But the efficiency of solar panels, considering their subsidies, the rare minerals used in their manufacture, their delivery and their maintenance... I'm confident it's a lot less than e.g. coa…

If you look at trajectory, coal is in decline and solar panels are being installed at a great clip. The decline in coal is mostly due to natural gas, but in the US, generation from solar tripled between 2013 and 2015.

https://www.eia.gov/electricity/monthly/epm_table_grapher.cf...

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#33
post #14

I don't want to poo-poo this achievement, but is another burnable fuel really what we want at this point?

Yes, because burnable fuels are usually far more energy dense than batteries, and also as others have pointed out because this process is carbon neutral. Maybe someday we'll have significantly better batteries, but until then..

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#34
> Authors: Mohammad Asadi, Kibum Kim, Cong Liu, Aditya Venkata Addepalli, Pedram Abbasi, Poya Yasaei, Patrick Phillips, Amirhossein Behranginia, José M. Cerrato, Richard Haasch, Peter Zapol, Bijandra Kumar, Robert F. Klie, Jeremiah Abiade, Larry A. Curtiss, Amin Salehi-Khojin

I wonder how many of the scientists who made this discovery would be banned from entering the United States by Donald Trump and the Republican Party.

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#35
"Nanotechnology" again. It's just surface chemistry, people. It's nice that they can do this in the lab, but as usual, the PR is excessive. "The ability to turn CO2 into fuel at a cost comparable to a gallon of gasoline would render fossil fuels obsolete." At least get to pilot plant stage before issuing statements like that.

Especially since UC Berkeley announced a similar breakthrough last year.[1] Wikipedia points out that artificial photosynthesis was first achieved in 1912, and some of the same claims were made back then. There are lots of artificial photosynthesis projects. One of the best was in 2011, the first "artificial leaf"[3]. It ran for 44 hours.

The usual questions apply. How efficient is this? Does the catalyst get used up, or crud up with contaminants, and if so, how fast? What limits the life of the system? What are the costs like? (Excessive catalyst cost has been a problem.) Is this better than all the other groups doing similar work?

Artificial photosynthesis may be useful someday, but this probably isn't the big breakthrough that makes it a commercial product. That may come, though.

[1] http://newscenter.lbl.gov/2015/04/16/major-advance-in-artifi... [2] https://en.wikipedia.org/wiki/Artificial_photosynthesis [3] https://www.acs.org/content/acs/en/pressroom/newsreleases/20...

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#36
post #5

In addition to lack of performance numbers, they misstate the amount of sunlight hitting earth by a factor of 10- it's supposed to be 1000 W/m2, not 100.

If you look at the (random) chart I found here[1] some places in the US are getting 6 - 7 sun hours (hours of insolation) so 7000 / 24 = 291 watts / square meter / day. So using a figure of 100 is quite reasonable when you consider that lots of places don't get that much sun.

1. http://www.solarpanelsplus.com/industry-professionals/insola...

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#37
post #9

This is wonderful! We're surrounded by life forms that turn water, CO2 and sunlight into energy. I figure there must be some way to harness this process. I wonder how much power a large tree takes in from its leaves. If we could interface with its root system, perhaps we could extract newly created starch, and either store it or burn it off. Image a huge concrete power plant with large trees growing out of it.

Isn't what you're describing called biodiesel? Palm oil, rapeseed oil, etc.

The problem is that however much humans need electrical energy, they need food a hell of a lot more. Electrical energy has to come from the land we're not feeding ourselves from, i.e. deserts, grasslands, rooftops.

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#38

Interesting that it's a combination of hydrogen and carbon monoxide that it produces. Wonder what the safety implications are.

Prior to the use of natural gas, such a mixture was used for lighting and cooking:

https://en.wikipedia.org/wiki/Coal_gas

I guess it won't be much different than natural gas from a safety standpoint.

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#39
post #30

Interesting that it's a combination of hydrogen and carbon monoxide that it produces. Wonder what the safety implications are.

As it says in the article: "the artificial leaf delivers syngas, or synthesis gas, a mixture of hydrogen gas and carbon monoxide. Syngas can be burned directly, or converted into diesel or other hydrocarbon fuels." Hydrogen and carbon dioxide are the feedstocks for the Fischer-Tropsch process, which produces conventional hydrocarbon fuel: https://en.wikipedia.org/wiki/Fischer%E2%80%93Tropsch_proces... In other words,…

Probably also worth noting that syngas is the primary input for the Haber-Bosch method used to generate the ammonia feedstock for most of our synthetic fertilizers. If you just take the CO and pump it underground then you are actually producing fertilizer for agriculture using a carbon negative process.

Re: Breakthrough solar cell captures CO2 and sunlight, produces burnable fuel

#40

> Authors: Mohammad Asadi, Kibum Kim, Cong Liu, Aditya Venkata Addepalli, Pedram Abbasi, Poya Yasaei, Patrick Phillips, Amirhossein Behranginia, José M. Cerrato, Richard Haasch, Peter Zapol, Bijandra Kumar, Robert F. Klie, Jeremiah Abiade, Larry A. Curtiss, Amin Salehi-Khojin I wonder how many of the scientists who made this discovery would be banned from entering the United States by Donald Trump and the Republican…

Possibly none. Those names don't suggest foreign birth let alone religion or race. Plenty of native-born Americans have such names.
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